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11 天
CJC | Concise Report- 中国海洋大学王洪玉课题组:可见光介导亚胺极性 ...
最近, 王洪玉课题组成功地开发了一种在可见光介导下,通过底物光敏策略和极性反转策略来合成 3,3-二取代氧化吲哚的无光催化剂的方法。初步的机理研究表明,靛红酮亚胺衍生物可以被可见光直接激发生成强氧化态,从而促进后续与Hantzsch酯的单电子转移(SET)过程,生成相应的α-氨基自由基中间体。α-氨基自由基中间体促进了随后的Giese ...
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29 天
Rh-Catalyzed trans-Divinylcyclopropane Rearrangement: An Approach to 1,5-Disubstituted 1,4 ...
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing ...
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