最近, 王洪玉课题组成功地开发了一种在可见光介导下,通过底物光敏策略和极性反转策略来合成 3,3-二取代氧化吲哚的无光催化剂的方法。初步的机理研究表明,靛红酮亚胺衍生物可以被可见光直接激发生成强氧化态,从而促进后续与Hantzsch酯的单电子转移(SET)过程,生成相应的α-氨基自由基中间体。α-氨基自由基中间体促进了随后的Giese ...
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing ...
Laboratory of Organo Catalysis and Synthesis, Department of Chemistry, Visvesvaraya National Institute of Technology (VNIT), Nagpur, Maharashtra 440010, India ...